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Organic Compounds Containing Nitrogen Test - 8

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Organic Compounds Containing Nitrogen Test - 8
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  • Question 1
    1 / -0

    How many primary amines are possible with the formula C4H11N?

    Solution

    Four (n-butylamine, isobutylamine, sec-butylamine and tert-butylamine)

     

  • Question 2
    1 / -0

    Which of the following form the weakest hydrogen bond?

    Solution

    The strength of H-bonds decreases in the following order.

    Primary amides > Carboxylic acids > Alcohols > Primary amines

    Thus, primary amines have the weakest H-bonds.

     

  • Question 3
    1 / -0

    Phenyl diazonium salts form azo dye with

    1. aniline
    2. phenol
    3. N, N-dimethyl aniline
    4. anisole

    Solution

    PhN ≡ N + is a weak electrophile that undergoes diazocoupling only with rings activated by -OH, -NH2, -NHR or -NR2. The ring is not sufficiently activated by -OCH3 and hence, anisole does not form azodye.

     

  • Question 4
    1 / -0

    Aromatic nitriles (ArCN) are not prepared by the reaction

    Solution

    Aryl halides do not react with KCN to form aryl cyanides, i.e.

     

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